- Family Services & Care, Pepperell
- Farms, Pepperell
- Fasteners & Miscellaneous Hardware Companies, Pepperell - Wholesale, Manufacturers & Suppliers
- Federal Administrative Agencies, Pepperell
- Federal Government, Pepperell
- Finance, Pepperell
- Financial Institutions, Pepperell
- Financial Services, Pepperell
- Fire Alarm Systems, Pepperell
- Fire Department, Pepperell
- Fire Extinguishers, Pepperell
- Firefighting Equipment & Supplies, Pepperell
- Fishing Tackle, Equipment & Supplies Stores, Pepperell - Lures, Rods, Reels, Baits, Poles & Fishing Gear
- Fitness, Pepperell
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- Floor Refinishing, Installation & Resurfacing, Pepperell - Hardwood, Laminate Flooring
- Flooring Contractors, Pepperell - Laminate, Hardwood, Carpet, Tile, Vinyl, Linoleum, etc
- Florists, Pepperell - Flower Shops
- Flowers & Plants, Pepperell
- Food & Beverage Stores & Services, Pepperell
- Food & Beverages - Wholesale & Retail, Pepperell
- Food Services, Pepperell
- Foundation Contractors, Pepperell - Foundation Repair & Install
- Fruit & Vegetable Markets, Wholesale & Retail, Pepperell
- Fuel Dealers & Gas Stations, Pepperell
- Full Service Breakfast Restaurants, Pepperell
- Funeral Services, Crematory & Cemetery, Pepperell - Funeral Homes & Directors
- Furniture Repair & Refinishing, Pepperell
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